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Merck
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文件

PX1235

Supelco

Piperidine

别名:

Piperidine, Hexahydropyridine

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About This Item

经验公式(希尔记法):
C5H11N
CAS号:
分子量:
85.15
MDL號碼:
分類程式碼代碼:
12191504
酶委員會索引編號:
203-813-0

蒸汽壓力

34 hPa ( 20 °C)

品質等級

化驗

≥99.5% (GC)

形狀

liquid

雜質

≤0.2% Water (H2O)

顏色

APHA: ≤50

pH值

12.6 (20 °C, 100 g/L in H2O)

bp

106 °C/1013 hPa

mp

-10.8 °C

轉變溫度

flash point 16 °C

密度

0.86 g/cm3 at 20 °C

運輸包裝

ambient

儲存溫度

room temp

InChI

1S/C5H11N/c1-2-4-6-5-3-1/h6H,1-5H2

InChI 密鑰

NQRYJNQNLNOLGT-UHFFFAOYSA-N

應用

Piperidine can be used as:
  • A Fmoc removal agent in solid-phase peptide synthesis.
  • An organic structure-directing agent in the synthesis of ferrierite zeolites and CoAPO (cobalt aluminophosphate) materials.
  • A reagent in the preparation of N-(2,4-dinitrophenyl)piperidine by reacting with 2,4-dinitrochlorobenzene via aromatic nucleophilic substitution reaction.

分析報告

Assay (GC): 99.5% min
Color (APHA): 50APHA max
Form: Clear liquid
Identity (IR-spectrum): Conforms
Water (H2O): 0.2% max

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

60.8 °F - closed cup

閃點(°C)

16 °C - closed cup


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Solvent effects on aromatic nucleophilic substitutions. Part 3. The kinetics of the reaction of 2, 4-dinitrochlorobenzene with piperidine in aprotic solvents
Mancini PME, et al.
J. Chem. Soc. Perkin Trans. II, (7), 1133-1138 (1984)
Synthesis of FER zeolite with piperidine as structure-directing agent and its catalytic application
Chu Weifeng, et al.
Chinese Journal of Catalysis, 38(11), 1880-1887 (2017)
Thermal investigations of CoAPO materials prepared by using piperidine as a structure-directing agent
Rajic N, et al.
Thermochimica Acta, 351(1-2), 119-124 (2000)
Omar F Luna et al.
Molecules (Basel, Switzerland), 21(11) (2016-11-18)
The deprotection step is crucial in order to secure a good quality product in Fmoc solid phase peptide synthesis. 9-Fluorenylmethoxycarbonyl (Fmoc) removal is achieved by a two-step mechanism reaction favored by the use of cyclic secondary amines; however, the efficiency

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