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Merck
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文件

T50202

Sigma-Aldrich

三丁基氯化锡

96%

别名:

TBTC, 氯化三丁基锡

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About This Item

线性分子式:
[CH3(CH2)3]3SnCl
CAS号:
1461-22-9
分子量:
325.51
Beilstein:
3535715
EC號碼:
215-958-7
MDL號碼:
MFCD00000521
分類程式碼代碼:
12352103
PubChem物質ID:
24900253
NACRES:
NA.22

蒸汽壓力

<0.01 mmHg ( 20 °C)

化驗

96%

折射率

n20/D 1.492 (lit.)

bp

171-173 °C/25 mmHg (lit.)

密度

1.2 g/mL at 25 °C (lit.)

SMILES 字串

CCCC[Sn](Cl)(CCCC)CCCC

InChI

1S/3C4H9.ClH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1

InChI 密鑰

GCTFWCDSFPMHHS-UHFFFAOYSA-M

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相关类别

應用

Tributyltin chloride (Bu3SnCl or tri-n-butylstannane) is an organotin compound that can be used as a reagent for:
  • The synthesis of fluorinated stannanes by reacting with fluorinated alkyl, aryl or vinyl halides using Zn or Cd catalyst via Barbier-type reaction.
  • The preparation of γ-hydroxyvinylstannanes, and indol-2-yltributylstannane.
  • The conversion of organozirconiums to organostannanes.

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - Skin Sens. 1B - STOT RE 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

226.4 °F - closed cup

閃點（°C）

108 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析证书(COA)

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Rita Jordão et al.
Environmental health perspectives, 123(8), 813-819 (2015-03-25)
The analysis of obesogenic effects in invertebrates is limited by our poor knowledge of the regulatory pathways of lipid metabolism. Recent data from the crustacean Daphnia magna points to three signaling hormonal pathways related to the molting and reproductive cycles
Fluorinated stannanes: Part 2. The stereospecific synthesis of fluorinated stannanes via a Barbier-type reaction between fluorinated halides and tributyltin chloride mediated by zinc or cadmium
Burton DJ and Jairaj V
Journal of Fluorine Chemistry, 126(5), 797-801 (2005)
Transmetalation from zirconium to tin: A facile preparation of organostannanes from organozirconiums
Kim S and Kim KH
Tetrahedron Letters, 36(21), 3725-3728 (1995)
A Route to the Preparation of γ -Hydroxyvinylstannanes
Lautens M and Huboux AH
Tetrahedron Letters, 31(22), 3105-3108 (1990)
Indol-2-yltributylstannane: a versatile reagent for 2-substituted indoles
Labadie SS and Teng E
The Journal of Organic Chemistry, 59(15), 4250-4254 (1994)
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Reagents for C–C Bond Formation

We carry a large variety of electrophiles and nucleophiles that are widely used in C–C bond-forming reactions. This group of products contains many organometallic reagents as well as commonly-used alkylating and acylating reagents.

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