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Merck
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文件

T32808

Sigma-Aldrich

硫酚

97%

别名:

巯基苯, 苯硫酚

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About This Item

线性分子式:
C6H5SH
CAS号:
108-98-5
分子量:
110.18
Beilstein:
506523
EC號碼:
203-635-3
MDL號碼:
MFCD00004826
分類程式碼代碼:
12352100
PubChem物質ID:
24900127
NACRES:
NA.22

蒸汽密度

3.8 (vs air)

品質等級

100

蒸汽壓力

1.4 mmHg ( 20 °C)

化驗

97%

折射率

n20/D 1.588 (lit.)

bp

169 °C (lit.)

mp

−15 °C (lit.)

密度

1.073 g/mL at 25 °C (lit.)

SMILES 字串

Sc1ccccc1

InChI

1S/C6H6S/c7-6-4-2-1-3-5-6/h1-5,7H

InChI 密鑰

RMVRSNDYEFQCLF-UHFFFAOYSA-N

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相关类别

一般說明

苯硫酚是一种有机硫化合物，可用作聚合物生产的中间体。

應用

苯硫酚可以在催化量的辛可宁存在下发生：
  • 不对称迈克尔加成到马来酸二异丙酯上形成（s）-（& # 8722；）-苯基硫代琥珀酸二异丙酯，它可进一步转化为（R）-（+）-3，4-环氧-1-丁醇。
  • 区域选择性和立体选择性1，4-加成到亚烯基环丙烷上，形成内型-或顺式-乙烯基硫化物加合物，这是合成卡拉哈烯酮的关键步骤。
  • 非对映选择性加成到 （S）-N-（& # 945；，& # 946；-不饱和羰基）-& # 947；-[（三苯甲基氧基）甲基]-& # 947；-丁内酯形成相应的& # 946；-（苯硫基）羧酸盐。

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 2 Dermal - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

122.0 °F - closed cup

閃點（°C）

50 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

分析证书(COA)

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Thiophenol additions to alkenylidenecyclopropanes. A novel synthesis of karahanaenone.
Cairns P M, et al.
Tetrahedron Letters, 23(13), 1405-1408 (1982)
Palladium-Catalyzed Regioselective Addition of Thiophenol to Conjugated Enynes. Efficient Syntheses of 2-(Phenylsulfinyl) and 2-(Phenylsulfonyl) 1, 3-Dienes.
Baeckvall J-E and Anna E
The Journal of Organic Chemistry, 59(20), 5850-5851 (1994)
A ratiometric fluorescent probe for selective detection of thiophenol derivatives
Li F, et al.
Spectrochimica Acta Part A: Molecular Spectroscopy, 271, 120870-120870 (2022)
Diastereoselective Thiophenol Addition to (S)-N-. alpha.,. beta.-Unsaturated carbonyl-. gamma.-[(trityloxy) methyl]-. gamma.-butyrolactams.
Tomioka K, et al.
The Journal of Organic Chemistry, 60(19), 6188-6190 (1995)
Ki-Jeong Kim et al.
Scientific reports, 10(1), 2119-2119 (2020-02-09)
The surface morphology and electronic structure of hexagonal graphene onion rings (HGORs), a modified graphene structure, were investigated to confirm the possibility as an efficient catalyst when compared to graphene. After confirming the formation of HGORs with a smaller width
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