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Merck

N1501

Sigma-Aldrich

新亚铜试剂

≥98%

别名:

2,9-二甲基-1,10-菲咯啉, DMPHEN

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About This Item

经验公式(希尔记法):
C14H12N2
CAS号:
分子量:
208.26
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥98%

形狀

crystalline

顏色

white to beige

SMILES 字串

Cc1ccc2ccc3ccc(C)nc3c2n1

InChI

1S/C14H12N2/c1-9-3-5-11-7-8-12-6-4-10(2)16-14(12)13(11)15-9/h3-8H,1-2H3

InChI 密鑰

IYRGXJIJGHOCFS-UHFFFAOYSA-N

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應用

新铜试剂可用作配体:      
  • 以 Au(I)为催化剂,对苯醇和烯丙醇进行有氧氧化反应,生成相应的羰基化合物。
  • 合成水(2,9-二甲基-1,10-邻二氮杂菲)NiCl2络合物,可作为前驱体,通过热分解方法制备均匀球形 NiO 纳米颗粒。     
  • 在锌催化的醛烯丙基化反应中制备具有高非对映选择性的α加成产物。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Shū Kobayashi et al.
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Zn(OH)2-catalyzed allylation reactions of aldehydes with allylboronates in aqueous media have been developed. In contrast to conventional allylboration reactions of aldehydes in organic solvents, the α-addition products were obtained exclusively. A catalytic cycle in which the allylzinc species was generated
Assem Barakat et al.
International journal of molecular sciences, 14(12), 23941-23954 (2013-12-20)
[NiCl2(C14H12N2)(H2O)] complex has been synthesized from nickel chloride hexahydrate (NiCl2·6H2O) and 2,9-dimethyl-1,10-phenanthroline (dmphen) as N,N-bidentate ligand. The synthesized complex was characterized by elemental analysis, infrared (IR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and differential thermal/thermogravimetric analysis (TG/DTA). The complex was further confirmed
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