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Merck

D106208

Sigma-Aldrich

3,4-二氢-2H-吡喃

97%

别名:

2,3,4-Trihydropyran, 2H-3,4-Dihydropyran, Dihydro-2H-pyran, Dihydropyran

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About This Item

经验公式(希尔记法):
C5H8O
CAS号:
分子量:
84.12
Beilstein:
103493
EC號碼:
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

2.9 (vs air)

品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.440 (lit.)

bp

86 °C (lit.)

mp

−70 °C (lit.)

密度

0.922 g/mL at 25 °C (lit.)

SMILES 字串

C1COC=CC1

InChI

1S/C5H8O/c1-2-4-6-5-3-1/h2,4H,1,3,5H2

InChI 密鑰

BUDQDWGNQVEFAC-UHFFFAOYSA-N

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應用

3,4-二氢-2h-吡喃可用作合成以下物质的反应物:
  • 在羟基苯磺酸-甲醛树脂催化剂存在的情况下由醇生成的四氢吡喃化产物。.
  • 在三氟乙酸存在的情况下与吡唑反应生成的四氢吡喃衍生物。.
  • 在阳离子交换树脂催化下通过与芳香胺的多米诺反应生成的1,2,3,4-四氢喹啉衍生物
  • 在存在FeCl3-NaI的情况下由芳基叠氮化物生成的四氢喹啉。

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1B

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

5.0 °F - closed cup

閃點(°C)

-15 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


分析证书(COA)

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FeCl3-NaI mediated reactions of aryl azides with 3, 4-dihydro-2H-pyran: a convenient synthesis of pyranoquinolines
Kamal A, et al.
Tetrahedron Letters, 45, 3507-3509 (2004)
O Kenrik Duru et al.
Journal of general internal medicine, 30(11), 1645-1650 (2015-05-07)
Reducing patient cost-sharing and engaging patients in disease management activities have been shown to increase uptake of evidence-based care. To evaluate the effect of employer purchase of a disease-specific plan with reduced cost-sharing and disease management (the Diabetes Health Plan/DHP)
Highly selective tetrahydropyranylation/dehydropyranylation of alcohols and phenols using porous phenolsulfonic acid-formaldehyde resin catalyst under solvent-free condition
Rajkumari K, et al.
Reactive and Functional Polymers, 149, 104519-104519 (2020)
Synthesis and Biological Evaluation of Novel Epothilone B Side Chain Analogues
Nicolaou K, et al
ChemMedChem, 10, 1974-1979 (2015)
Domino reaction of anilines with 3, 4-dihydro-2H-pyran catalyzed by cation-exchange resin in water: an efficient synthesis of 1, 2, 3, 4-tetrahydroquinoline derivatives
Chen L, et al.
Green Chemistry, 5, 627-629 (2003)

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