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ALD00400

Sigma-Aldrich

2-氯-6-碘苯甲酸

95%

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About This Item

经验公式（希尔记法）:
C7H4ClIO2
CAS号:
13420-63-8
分子量:
282.46
MDL编号:
MFCD06808823
UNSPSC代码:
12352100
PubChem化学物质编号:
329772665
NACRES:
NA.22

质量水平

100

方案

95%

表单

solid

反应适用性

reagent type: ligand
reaction type: C-H Activation

SMILES字符串

OC(C1=C(Cl)C=CC=C1I)=O

InChI

1S/C7H4ClIO2/c8-4-2-1-3-5(9)6(4)7(10)11/h1-3H,(H,10,11)

InChI key

KNWHWEKCHWFXFZ-UHFFFAOYSA-N

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应用

The following building block was synthesized via a C-H activation method developed by Yu and coworkers. The method was incorporated using the Yu-Wasa Auxiliary (Aldrich 791806) and I2 as the sole oxidant for ortho-iodination from the corresponding benzoic acid derivative.

其他说明

Iodination Method Eases Route To Radiolabeled Drugs

象形图

Skull and crossbones
GHS06

警示用语：

Danger

危险声明

H301,H319

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKBT7517V

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Xiao-Chen Wang et al.
Journal of the American Chemical Society, 135(28), 10326-10329 (2013-07-11)
Pd-catalyzed ortho-C-H iodination directed by a weakly coordinating amide auxiliary using I2 as the sole oxidant was developed. This reaction is compatible with a wide range of heterocycles including pyridines, imidazoles, oxazoles, thiazoles, isoxazoles, and pyrazoles.

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