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文件

915157

iPr-PDI

Name: iPr-PDI
Brand: ALDRICH

≥95%

别名:

N,N-Bis(2,6-diisopropylphenyl)perylene-3,4,9,10-bis(dicarboximide)

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About This Item

经验公式（希尔记法）:

C₄₈H₄₂N₂O₄

CAS号:

82953-57-9

分子量:

710.86

分類程式碼代碼:

12352101

NACRES:

NA.22

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268615

3-氨基丙基磷酸

Sigma-Aldrich

264229

N,N'-双(2,5-二叔丁基苯基)-3,4,9,10-苝二甲酰亚胺

Sigma-Aldrich

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Di-PDI

品質等級

100

化驗

≥95%

形狀

powder

mp

>300 °C

儲存溫度

−20°C

應用

iPr-PDI is a perylene based organic photocatalyst with a variety of demonstrated uses, including the reduction of aryl halides and the iodoperfluoroalkylation of alkenes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Visible-Light-Mediated Iodoperfluoroalkylation of Alkenes in Flow and Its Application to the Synthesis of a Key Fulvestrant Intermediate.

Cristian Rosso et al.

Organic letters, 21(13), 5341-5345 (2019-06-30)

Two efficient continuous flow iodoperfluoroalkylation methods are described: using 0.05 mol % perylene diimide (PDI) photocatalyst under 450 nm irradiation or substoichiometric triethylamine under 405 nm irradiation. These methods enable dramatically elevated productivity versus batch processes. The triethylamine-mediated method is

Reduction of aryl halides by consecutive visible light-induced electron transfer processes.

Indrajit Ghosh et al.

Science (New York, N.Y.), 346(6210), 725-728 (2014-11-08)

Biological photosynthesis uses the energy of several visible light photons for the challenging oxidation of water, whereas chemical photocatalysis typically involves only single-photon excitation. Perylene bisimide is reduced by visible light photoinduced electron transfer (PET) to its stable and colored

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iPr-PDI