所有图片(3)

文件

908444

DPZ

Name: DPZ
Brand: ALDRICH

95%

别名:

5,6-Bis(5-methoxythiophen-2-yl)pyrazine-2,3-dicarbonitrile

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所有图片(3)

About This Item

经验公式（希尔记法）:

C₁₆H₁₀N₄O₂S₂

CAS号:

1818245-74-7

分子量:

354.41

分類程式碼代碼:

12352101

NACRES:

NA.22

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化驗

95%

形狀

(Powder or Solid or Chunks)

反應適用性

reaction type: Photocatalysis
reagent type: catalyst

儲存溫度

2-8°C

應用

DPZ is an organic photoredox catalyst used in a variety of visible-light mediated transformations including in asymmetric dual catalytic systems.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Conjugate Addition-Enantioselective Protonation of N-Aryl Glycines to α-Branched 2-Vinylazaarenes via Cooperative Photoredox and Asymmetric Catalysis.

Yanli Yin et al.

Journal of the American Chemical Society, 140(19), 6083-6087 (2018-04-11)

An enantioselective protonation strategy has been successfully applied to the synthesis of chiral α-tertiary azaarenes. With a dual catalytic system involving a chiral phosphoric acid and a dicyanopyrazine-derived chromophore (DPZ) photosensitizer that is mediated by visible light, a variety of

Controllable Chemoselectivity in Visible-Light Photoredox Catalysis: Four Diverse Aerobic Radical Cascade Reactions.

Xinfei Liu et al.

Angewandte Chemie (International ed. in English), 54(39), 11443-11447 (2015-07-28)

Reported is the controllable selectivity syntheses of four distinct products from the same starting materials by visible-light photoredox catalysis. By employing a dicyanopyrazine-derived chromophore (DPZ) as photoredox catalyst, an aerobic radical mechanism has been developed, and allows the reactions of

Organocatalytic Enantioselective Addition of α-Aminoalkyl Radicals to Isoquinolines.

Xiangyuan Liu et al.

Organic letters, 20(19), 6298-6301 (2018-09-27)

With a dual organocatalytic system involving a chiral phosphoric acid and a dicyanopyrazine-derived chromophore (DPZ) photosensitizer and under the irradiation with visible light, an enantioselective Minisci-type addition of α-amino acid-derived redox-active esters (RAEs) to isoquinolines has been developed. A variety

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DPZ