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![4-[(苯氨基)羰基]苯硼酸频哪醇酯 97%](/deepweb/assets/sigmaaldrich/product/structures/337/186/9c84d4e6-1ad2-4191-8e05-28e107637cf0/640/9c84d4e6-1ad2-4191-8e05-28e107637cf0.png)
化驗
95% (HPLC)
品質等級
形狀
solid
mp
29-34 °C
儲存溫度
2-8°C
SMILES 字串
O=S(C1=CC=CC=N1)(F)=O
InChI
1S/C5H4FNO2S/c6-10(8,9)5-3-1-2-4-7-5/h1-4H
InChI 密鑰
FCFXLXGZHDHJLB-UHFFFAOYSA-N
應用
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
商品
The prevalence of organofluorine compounds in industry and drug design necessitates the ability to introduce C–F bonds to molecules.
相关内容
The prevalence of organofluorine compounds in industry and drug design necessitates the ability to introduce C–F bonds to molecules.
Research in the Doyle group focuses on two areas: nucleophilic fluorination and nickel catalysis. The Doyle group has developed several reagents that advance these research areas. In fluorination, 2-pyridinesulfonyl fluoride (PyFluor) can be used for the mild deoxyfluorination of primary and secondary alcohols, a procedure which is normally accomplished by the sensitive reagent DAST. In nickel catalysis, the Doyle group has developed a modular, air-stable nickel precatalyst, [(TMEDA)Ni(o-tolyl)Cl], which has broad utility for a wide variety of reactions. This precatalyst can be used in place of Ni(cod)2, NiCl2, as well as other reported precatalysts. Doyle has also reported electron-deficient olefin ligands as a new class of ligand for accelerated reductive elimination. In particular, the sultam-derived ligand Fro-DO has been found to be critical for high yields in the cross-coupling of tertiary aziridines to form quaternary centers.
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