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Merck

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791105

Zinc chloromethanesulfinate

95% (H-NMR)

别名:

Baran MCMS Reagent

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10 g
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$962.00

关于此项目

经验公式(希尔记法):
C2H4Cl2O4S2Zn
化学文摘社编号:
分子量:
292.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Assay:
95% (H-NMR)
Form:
solid

$962.00


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Quality Segment

assay

95% (H-NMR)

form

solid

reaction suitability

reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent

mp

190-195 °C

functional group

chloro, sulfinic acid

storage temp.

2-8°C

SMILES string

ClCS(O[Zn]OS(CCl)=O)=O

InChI

1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

InChI key

HEKATMPPXNXYJU-UHFFFAOYSA-L

Application

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

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此商品
745480771406746118
assay

95% (H-NMR)

assay

95%

assay

-

assay

95%

reaction suitability

reaction type: C-C Bond Formation, reagent type: diversification reagent, reagent type: catalyst
reaction type: C-H Activation

reaction suitability

reaction type: Allylation, reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: diversification reagent

reaction suitability

reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation

reaction suitability

reaction type: C-C Bond Formation, reagent type: catalyst
reaction type: C-H Activation, reagent type: linker

form

solid

form

solid

form

solid

form

solid

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

2-8°C

mp

190-195 °C

mp

161-166 °C

mp

151-157 °C

mp

-

functional group

chloro

functional group

sulfinic acid

functional group

-

functional group

azide, fluoro, sulfinic acid


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

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