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Merck
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文件

768103

Sigma-Aldrich

Dichlorobis(di-tert-butylphenylphosphine)palladium(II)

95%

别名:

(SP-4-1)-Bis[bis(1,1-dimethylethyl)phenylphosphine]dichloropalladium, trans-Dichlorobis(di-tert-butylphenylphosphine)palladium, trans-Dichlorobis(di-tert-butylphenylphosphine)palladium(II)

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About This Item

经验公式（希尔记法）:
C28H46Cl2P2Pd
CAS号:
34409-44-4
分子量:
621.94
MDL號碼:
MFCD09953450
分類程式碼代碼:
12161600
PubChem物質ID:
329767356
NACRES:
NA.22

化驗

95%

形狀

solid

反應適用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

260-264 °C (decomposition)

SMILES 字串

Cl[Pd]Cl.CC(C)(C)P(c1ccccc1)C(C)(C)C.CC(C)(C)P(c2ccccc2)C(C)(C)C

InChI

1S/2C14H23P.2ClH.Pd/c2*1-13(2,3)15(14(4,5)6)12-10-8-7-9-11-12;;;/h2*7-11H,1-6H3;2*1H;/q;;;;+2/p-2

InChI 密鑰

QNNRAWADYXIGHE-UHFFFAOYSA-L

相关类别

應用

Effective catalyst for cross-coupling reactions.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Xavier Guinchard et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(23), 5793-5798 (2009-04-28)
We describe the preparation of a series of new potassium trifluoroborates 1 and the study of their behaviour in a Pd(0)-catalyzed cross-coupling reaction. We found that compounds 1 are endowed with original properties as they behave as nucleophilic cross-coupling partners
Anil S Guram et al.
The Journal of organic chemistry, 72(14), 5104-5112 (2007-06-07)
The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-substituted heteroaryl chlorides with a diverse range of aryl/heteroaryl boronic acids. The coupling reactions catalyzed by
Anil S Guram et al.
Organic letters, 8(9), 1787-1789 (2006-04-21)
[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides and heteroatom-substituted six-membered heteroaryl chlorides with a diverse range of

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