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化驗
96% (GC)
形狀
liquid
包含
copper as stabilizer
成份
(copper wire added to bulk material for stabilization)
儲存條件
under inert gas
折射率
n20/D 1.518
密度
1.388 g/mL at 25 °C
儲存溫度
−20°C
SMILES 字串
CC(=O)SCCCCBr
InChI
1S/C6H11BrOS/c1-6(8)9-5-3-2-4-7/h2-5H2,1H3
InChI 密鑰
ABARMQVSPZAYRI-UHFFFAOYSA-N
一般說明
S-(4-Bromobutyl) thioacetate is used as a precursor in the formation of organic self-assembled monolayers (SAMs) on metals. Deprotection reactions can then converts the thioacetate group to thiol. These are chemisorbed onto metal surfaces to form self-assembled monolayers with a high degree of structural order. They are often used as a molecular template to form functional nanostructures.
應用
Used in the formation of Self-Assembled Monolayers on gold electrodes to modify its work function.
特點和優勢
High chemical stability in air or solution. Thioacetate prevents undesirable oxidation of thiol groups in oxygen containing atmosphere. Forms homogeneous interface structure in SAMs.
訊號詞
Warning
危險分類
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
The Thioacetate-Functionalized Self-Assembled Monolayers on Au: Toward High-Performance Ion-Selective Electrode for Ag
Jin, J., Zhou, W. J., Chen, Y., Liu, Y. L., Sun, X. Q., & Xi, H. T.
Bull. Korean Chem. Soc., 35(2), 601-601 (2014)
Formation and Structure of Self-Assembled Monolayers of Octylthioacetates on Au (111) in Catalytic Tetrabutylammonium Cyanide Solution
Park, T., Kang, H., Choi, I., Chung, H., Ito, E., Hara, M., & Noh, J.
Bull. Korean Chem. Soc., 30(2), 441-441 (2009)
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