跳转至内容
Merck

719013

Sigma-Aldrich

[(1-哌啶基)甲基]三氟硼酸钾

internal salt

登录查看公司和协议定价


About This Item

经验公式(希尔记法):
C6H13BF3N
分子量:
166.98
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

形狀

solid

mp

134-149 °C

SMILES 字串

F[B-](F)(F)C[NH+]1CCCCC1

InChI

1S/C6H12BF3N/c8-7(9,10)6-11-4-2-1-3-5-11/h1-6H2/q-1/p+1

InChI 密鑰

PFMNVTAJBBIDDU-UHFFFAOYSA-O

應用

(Piperidinium-1-ylmethyl)trifluoroborate can be used as a reagent in the palladium-catalyzed Suzuki-cross coupling reaction with aryl and heteroaryl halides/mesylates to prepare methylpiperidinyl derivatives.
Organotrifluoroborate involved in Suzuki-Miyaura cross-coupling and cross coupling with mesylated phenol derivatives

Organotrifluoroborates as versatile and stable boronic acid surrogates.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Reinvestigation of aminomethyltrifluoroborates and their application in Suzuki- Miyaura cross-coupling reactions
Raushel J, et al.
The Journal of Organic Chemistry, 76(8), 2762-2769 (2011)
Cross-coupling of mesylated phenol derivatives with potassium ammonio-and amidomethyltrifluoroborates
Molander GA and Beaumard F
Organic Letters, 13(5), 1242-1245 (2011)

商品

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

相关内容

These bench stable Potassium Organotrifluoroborates are useful for Suzuki-Miyaura cross-coupling reactions and have also been used for a variety of other C-C bond forming reactions. Importantly, these reagents are compatible with a wide range of functional groups and are stable to many commonly used and harsh reaction conditions.

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门