693979

(1E,2E)-1,2-双(2,6-二异丙苯基亚氨基)乙烷

90%

• 别名: N,N′-双(2,6-二异丙基苯基))-1,4-二氮杂丁二烯, N,N′-双(2,6-二异丙基苯基)乙二亚胺, 乙二醛双(2,6-二异丙基苯胺)
• 线性分子式: (C₃H₇)₂C₆H₃NCHCHNC₆H₃(C₃H₇)₂
• CAS号: 74663-75-5
• 分子量: 376.58
• MDL编号: MFCD03838856
• UNSPSC代码: 12352300
• PubChem化学物质编号: 329761636
• NACRES: NA.22

属性

• 方案: 90%
• 表单: solid
• 反应适用性: reagent type: ligand
• mp: 105-109 °C
• SMILES字符串: CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
• InChI: 1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
• InChI key: JWVIIGXMTONOFR-DPCVLPDWSA-N

说明

应用

• Reactant in preparation of derived ruthenium olefin metathesis catalysts
• N-cyclic carbene ligand

Catalyst in:

• Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
• Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
• N-arylation of aromatic amines
• Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions

安全信息

• 储存分类代码: 13 - Non Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable