598089

环戊二烯基二羰基(四氢呋喃)铁(II)四氟硼酸

• 经验公式（希尔记法）: C₁₁H₁₃BF₄FeO₃
• CAS号: 63313-71-3
• 分子量: 335.87
• UNSPSC代码: 12352300
• PubChem化学物质编号: 24881737
• NACRES: NA.22

属性

• 反应适用性: core: iron; reagent type: catalyst
• mp: 110 °C (dec.) (lit.)
• 储存温度: 2-8°C
• SMILES字符串: [Fe+].[C-]#[O+].[C-]#[O+].F[B-](F)(F)F.[CH]1[CH][CH][CH][CH]1.C2CCOC2
• InChI: 1S/C5H5.C4H8O.2CO.BF4.Fe/c2*1-2-4-5-3-1;2*1-2;2-1(3,4)5;/h1-5H;1-4H2;;;;/q;;;;-1;+1
• InChI key: UEQAYXWNQGYVGN-UHFFFAOYSA-N

说明

应用

Catalyst for:

• Preparation of β-keto esters via Lewis acid-catalyzed addition of Et diazoacetate to arylaldehydes
• Iron mediated nitrenoid transfer
• Lewis acid catalyzed aziridination, cyclopropanation, and insertion reaction with diazo compounds
• Diels-Alder reaction of dienes with enones

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H302 + H312 + H332
• 预防措施声明: P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
• 危险分类: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable