547794

三[N,N-双(三甲基硅烷)胺]钕(III)

97%

• 别名: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
• 线性分子式: Nd(N(Si(CH₃)₃)₂)₃
• CAS号: 148274-47-9
• 分子量: 625.39
• MDL编号: MFCD03427089
• UNSPSC代码: 12352300
• PubChem化学物质编号: 24878980

属性

• 方案: 97%
• 表单: solid
• 反应适用性: reagent type: catalyst; core: neodymium
• mp: 156-159 °C (lit.)
• SMILES字符串: C[Si](C)(C)N([Nd](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
• InChI: 1S/3C6H18NSi2.Nd/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
• InChI key: LWKIKGQVWYVALF-UHFFFAOYSA-N

说明

应用

Reagent for synthesis of:

• Imidophosphinate complexes of lanthanides
• Neodymium methoxides containing thienyl substituents
• Phenylene-bridged binuclear organolanthanide complexes
• Near-infrared photoluminescent neodymium(III) complexes

Reagent for:

• Rare-earth metal carboxylate-based catalysts
• Regioselective C-H activation

安全信息

• 象形图: GHS02,GHS05
• 警示用语：: Danger
• 危险声明: H228,H261,H314
• 预防措施声明: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• 危险分类: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• 补充剂危害: EUH014
• 储存分类代码: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 闪点(°F): 36.0 °F - closed cup
• 闪点(°C): 2.2 °C - closed cup
• 个人防护装备: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges