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Merck
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文件

536490

Sigma-Aldrich

2- 叔 -丁亚胺-2-二乙氨基-1,3-二甲基二氢-1,3,2-二氮杂膦，聚合物结合

200-400 mesh, extent of labeling: 2.0-2.5 mmol/g loading, 1 % cross-linked

别名:

BEMP 树脂

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About This Item

MDL號碼:
MFCD03095934
分類程式碼代碼:
12352128
PubChem物質ID:
24878163
NACRES:
NA.22

交聯

1 % cross-linked

反應適用性

reaction type: solution phase peptide synthesis
reactivity: proton reactive

標籤範圍

2.0-2.5 mmol/g loading

粒徑

200-400 mesh

SMILES 字串

C=Cc1ccccc1.C=Cc2ccc(C=C)cc2.CCN(CC)P3(=NC(C)(C)C)N(C)CCCN3Cc4ccccc4

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相关类别

應用

Phosphazene Bases: a Family of Extremely Strong, Non-Ionic, Non-Charged Nitrogen–Bases
用于弱酸性杂环化合物的脱质子化和 N-烷基化反应的聚合物负载碱。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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1 of 1

磷腈配体 P2-Et ≥98.0% (NT)

Sigma-Aldrich

79417

磷腈配体 P2-Et

Ying Wang et al.
Organic letters, 7(5), 925-928 (2005-02-25)
1,2,4-Oxadiazoles can be rapidly and efficiently synthesized from a variety of readily available carboxylic acids and amidoximes using either method A or method B. The use of commercially available polymer-supported reagents combined with microwave heating resulted in high yields and
A study of polymer-supported bases for the solution phase synthesis of glycosyl trichloroacetimidates.
Jose Luis Chiara, Lourdes Encinas and Beatriz Diaz
Tetrahedron Letters, 46, 2445-2448 (2005)
A convenient 'catch and release' synthesis of fused 2-alkylthio-pyrimidinones mediated by polymer-bound BEMP.
Gregory L. Adams et al.
Tetrahedron Letters, 44, 5041-5045 (2003)
Serena Gabrielli et al.
Molecules (Basel, Switzerland), 21(6) (2016-06-18)
Quinoline-2-carboxylates are an important subclass of quinoline derivatives largely present in a variety of biologically active molecules, as well as useful ligands in metal-catalyzed reactions. Herein, we present a new one-pot protocol for synthesizing this class of derivatives starting from

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