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499552

锌制备

Name: 锌 制备
Brand: ALDRICH

5 g/dL Zn⁺² in THF, highly reactive Rieke^®metal

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About This Item

线性分子式:

CAS号:

7440-66-6

分子量:

65.39

MDL號碼:

MFCD00011291

分類程式碼代碼:

12161600

PubChem物質ID:

24873288

NACRES:

NA.22

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异丙基氯化镁氯化锂络合物溶液

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SAFC

703559

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Sigma-Aldrich

205273

四异丙醇钛

Sigma-Aldrich

230111

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Sigma-Aldrich

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Sigma-Aldrich

429406

氯化铈(III)

Sigma-Aldrich

411019

四甲基乙二胺

Sigma-Aldrich

697257

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反應適用性

core: zinc
reagent type: catalyst

濃度

5 g/dL Zn⁺² in THF

密度

0.949 g/mL at 25 °C

儲存溫度

2-8°C

SMILES 字串

[Zn]

InChI

1S/Zn

InChI 密鑰

HCHKCACWOHOZIP-UHFFFAOYSA-N

應用

Rieke^®锌可用于还原常见有机官能团，如芳硝基化合物、共轭醛、芳炔和苯丙炔酸酯。

法律資訊

Rieke Metals, Inc.公司产品。
Rieke 是Rieke Metals, Inc.公司的注册商标。

Rieke is a registered trademark of Rieke Metals, Inc.

象形圖

GHS02,GHS08,GHS07,GHS09

訊號詞

Danger

危險聲明

H225,H302,H319,H335,H336,H351,H411

防範說明

P202 - P210 - P273 - P301 + P312 - P305 + P351 + P338 - P308 + P313

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

標靶器官

Central nervous system, Respiratory system

安全危害

EUH019

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

1.0 °F - closed cup

閃點（°C）

-17.22 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Rieke zinc as a reducing agent for common organic functional groups

Kroemer J, et al.

Tetrahedron Letters, 47(36), 6339-6341 (2006)

An alternative way for the evaluation of zinc status in the elderly; nail zinc levels and relationship with Alzheimer's disease.

M E Kuyumcu et al.

European review for medical and pharmacological sciences, 17(11), 1467-1471 (2013-06-19)

Zinc is one of the most important elements for human body. Zinc deficiency can occur in any age, if it is seen in elderly its clinical results can be more harmful due to already diminished functions. Some studies showed zinc

A viewpoint about the treatment of Wilson's disease.

Abdul Qayyum Rana et al.

The Canadian journal of neurological sciences. Le journal canadien des sciences neurologiques, 40(4), 612-614 (2013-06-22)

Synthesis and reactivity of Zn-biphenyl metal-organic frameworks, introducing a diphenylphosphino functional group.

Marco Ranocchiari et al.

Chimia, 67(6), 397-402 (2013-08-16)

Structural features, synthesis, and reactivity of Zn-biphenyl metal-organic frameworks with MOF-5 topology are presented to show the chemical flexibility of such materials and to demonstrate the challenges that can be encountered and solved to avoid interpenetration. We introduce the synthesis

Impact of cadmium and zinc on root system of Lolium perenne and Trifolium repens.

T Lambrechts et al.

Communications in agricultural and applied biological sciences, 78(1), 19-24 (2013-07-24)

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商品

Rieke^® Highly Reactive Metals

Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.

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锌制备