濃度
0.5 M in THF
密度
1.018 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
CCOC(=O)c1ccc([Zn]I)cc1
InChI
1S/C9H9O2.HI.Zn/c1-2-11-9(10)8-6-4-3-5-7-8;;/h4-7H,2H2,1H3;1H;/q;;+1/p-1
InChI 密鑰
QKMCGFIQAJUQIL-UHFFFAOYSA-M
應用
4-(Ethoxycarbonyl)phenylzinc iodide can be used as:
- A substrate in the transition metal-catalyzed cross-coupling reactions with unsaturated thioethers and thiomethyl-substituted N-heterocycles.
- A starting material in the synthesis of indazole derived glucagon receptor antagonists.
- A substrate in the Pd-catalyzed synthesis of 5-aryl-2-furaldehydes by reacting with 5-bromo-2-furaldehyde.
法律資訊
Rieke® Metals, Inc. 产品。®Rieke Metals, Inc. 的注册商标。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
標靶器官
Respiratory system
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
1.0 °F - closed cup
閃點(°C)
-17.2 °C - closed cup
Pd-catalyzed cross-coupling of functionalized organozinc reagents with thiomethyl-substituted heterocycles
Organic Letters, 11(18), 4228-4231 (2009)
Pd-and Ni-Catalyzed Cross-Coupling Reactions of Functionalized Organozinc Reagents with Unsaturated Thioethers
Chemistry?A European Journal , 17(10), 2948-2956 (2011)
Discovery of potent and orally bioavailable indazole-based glucagon receptor antagonists for the treatment of type 2 diabetes
Bioorganic & Medicinal Chemistry Letters, 29(20), 126668-126668 (2019)
A convenient synthesis of 5-aryl-and 5-heteroaryl-2-furaldehydes by the cross-coupling reaction of organozincs
Tetrahedron Letters, 51(19), 2657-2659 (2010)
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