479438

四甲基环戊二烯锂

• 线性分子式: LiC₅H(CH₃)₄
• CAS号: 82061-21-0
• 分子量: 128.14
• MDL號碼: MFCD00269824
• 分類程式碼代碼: 12352300
• PubChem物質ID: 24871617
• NACRES: NA.22

属性

• 反應適用性: reagent type: ligand
• mp: >350 °C (lit.)
• SMILES 字串: [Li].C[C]1[CH][C](C)[C](C)[C]1C
• InChI: 1S/C9H13.Li.H/c1-6-5-7(2)9(4)8(6)3;;/h5H,1-4H3;;
• InChI 密鑰: PTQWRLJKGBNMJV-UHFFFAOYSA-N

说明

應用

Reactant for synthesis of:

• Cyclopentadienylphosphanes
• Ansa-cyclopentadienyl-phenoxy titanium(IV) complexes
• Titanium and zirconium complexes
• Hafnocene catalysts

Reactant with SiH-functionalized cyclopentadienes

Reactant in the reduction of beta-diketiminato-titanium(III) complexes

安全信息

• 象形圖: GHS02
• 訊號詞: Danger
• 危險聲明: H250
• 防範說明: P222 - P231 - P422
• 危險分類: Pyr. Sol. 1
• 儲存類別代碼: 4.2 - Pyrophoric and self-heating hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Faceshields, Gloves