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Merck
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文件

463779

Sigma-Aldrich

氯化钌 (III) 水合物

99.98% trace metals basis

别名:

三氯化钌

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About This Item

线性分子式:
RuCl3 · xH2O
CAS号:
14898-67-0
分子量:
207.43 (anhydrous basis)
EC號碼:
233-167-5
MDL號碼:
MFCD00149844
分類程式碼代碼:
12352302
PubChem物質ID:
24870096
NACRES:
NA.23

品質等級

100

化驗

99.98% trace metals basis

形狀

powder and chunks

反應適用性

reagent type: catalyst
core: ruthenium

雜質

≤250.0 ppm Trace Metal Analysis

SMILES 字串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI 密鑰

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相关类别

一般說明

Ruthenium(III) chloride hydrate exhibits excellent catalytic activity, attributed to the redox properties of ruthenium suitable for fuel cells and other electrochemical devices. It has ability to facilitate charge transfer and exhibit photoactive behavior.

應用

Ruthenium(III) chloride hydrate can be used:
  • As a precursor to prepare ultralow Ru loaded graphene aerogel that exhibits electrocatalytic performance in the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR).
  • As a dopant to prepare Ru-doped TiO2 electron transport layer for mesoscopic perovskite solar cell by spin-coating technique. This helps to enhance photoconversion efficiency and air stability.
  • To fabricate ultra-uniform Ru nanocluster catalyst via small-molecule self-assembly pyrolysis method. These catalysts exhibit excellent hydrogen evolution activity in Zinc air batteries under all pH conditions.

其他說明

可溶型

訊號詞

Danger

危險聲明

H302,H314,H411

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Fujita, S.-I., et al.
J. Catal., 255, 95-95 (2004)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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