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Merck

463086

Sigma-Aldrich

三氟化硼

electronic grade, ≥99.99%

别名:

三氟化硼, 三氟硼, 三氟硼烷, 氟化硼

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About This Item

经验公式(希尔记法):
BF3
CAS号:
分子量:
67.81
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

等級

electronic grade

蒸汽密度

2.38 (21 °C, vs air)

化驗

≥99.99%

形狀

gas

反應適用性

core: boron
reagent type: catalyst

雜質

<10 ppm Carbon dioxide (CO2)
<10 ppm Nitrogen(N2) + oxygen (O2)
<10 ppm Other Sulfates
<10 ppm Sulfur dioxide (SO2)
<50 ppm Silicon tetrafluoride (SiF4)

bp

−100 °C (lit.)

mp

−127 °C (lit.)

轉變溫度

critical temperature −12.3 °C

SMILES 字串

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI 密鑰

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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一般說明

基础材料的原子序数:5 Boron

應用

最近应用于路易斯酸活化晶界增强CaF2 电导率的研究。

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訊號詞

Danger

危險聲明

危險分類

Acute Tox. 2 Inhalation - Eye Dam. 1 - Press. Gas Compr. Gas - Skin Corr. 1A

安全危害

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 1

個人防護裝備

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)


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Solid State Ionics, 86-88, 581-581 (1996)
Ramanathan Rajaganesh et al.
Carbohydrate research, 345(12), 1649-1657 (2010-06-29)
BF(3).Et(2)O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-beta-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC(50) approximately 77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of
Joseph J Topczewski et al.
The Journal of organic chemistry, 74(18), 6965-6972 (2009-08-25)
The first total synthesis of (+)-schweinfurthin B, a potent and differentially active cytotoxic agent, has been accomplished. Completion of the synthesis required just 16 steps in the longest linear sequence from commercially available vanillin. Key synthetic transformations included a Shi
G K Surya Prakash et al.
Organic letters, 13(15), 4128-4131 (2011-07-14)
The one-pot synthesis of 1,1,1-trifluoro- and 1,1-difluoro-2,2-diarylethanes from arenes and fluorinated hemiacetals in the BF(3)-H(2)O system is described. The reaction is simple, clean, and convenient, eliminating the use of organic solvents and other expensive acid systems. BF(3)-H(2)O is economic, is
Brieuc Guillerm et al.
Macromolecular rapid communications, 33(19), 1600-1612 (2012-07-05)
Polyoxazolines (POx) are increasingly being studied as polymeric building blocks due to the possibility of affording tunable properties. Additionally, as the biocompatibility and stealth behavior of POx are similar to that of poly(ethylene glycol) (PEG), it has become challenging to

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