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447145

Sigma-Aldrich

硼烷二甲基硫醚络合物 溶液

5.0 M in diethyl ether

别名:

BMS, 三氢 [硫代双 [甲烷]] 硼

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About This Item

线性分子式:
(CH3)2S · BH3
CAS号:
13292-87-0
分子量:
75.97
Beilstein:
3663489
MDL號碼:
MFCD00013189
分類程式碼代碼:
12352112
PubChem物質ID:
24868320
NACRES:
NA.22

反應適用性

reagent type: reductant

濃度

5.0 M in diethyl ether

bp

~34 °C

密度

0.789 g/mL at 25 °C

官能基

thioether

儲存溫度

2-8°C

SMILES 字串

B.CSC

InChI

1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3

InChI 密鑰

RMHDLBZYPISZOI-UHFFFAOYSA-N

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應用

用作区域选择性还原剂的反应物

涉及的反应物：
  • 硼氢化/氧化
笼状化合物的合成
Borane dimethyl sulfide complex can be used in the preparation of:
  • An amine-based polymer for CO2 uptake.
  • Amine-modified electrospun ultrafine fibers used to remove methyl orange from water.
  • Thexylborane, a key intermediate for the synthesis of polyethylene derived star copolymers and terpolymers.

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 1 - Repr. 1B - STOT SE 3 - Water-react 1

標靶器官

Central nervous system

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類（WGK）

WGK 1

閃點（°F）

-31.0 °F - closed cup

閃點（°C）

-35 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves

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分析证书(COA)

Lot/Batch Number
SHBK0104
SHBJ7769
SHBF0672V
SHBB2426
23796JM

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Synthesis of well-defined polyethylene-based 3-miktoarm star copolymers and terpolymers
Zhang Z, et al.
Macromolecules, 49(7), 2630-2638 (2016)
Amine modified electrospun PIM-1 ultrafine fibers for an efficient removal of methyl orange from an aqueous system
Satilmis B and Uyar T
Applied Surface Science, 453, 220-229 (2018)
Enhancement of CO2 affinity in a polymer of intrinsic microporosity by amine modification
Mason CR, et al.
Macromolecules, 47(3), 1021-1029 (2014)
A Burchert et al.
Leukemia, 29(6), 1331-1335 (2015-02-26)
A minority of chronic myeloid leukemia (CML) patients is capable of successfully discontinuing imatinib. Treatment modalities to increase this proportion are currently unknown. Here, we assessed the role of interferon alpha 2a (IFN) on therapy discontinuation in a previously reported
Kathleen C Rollet-Kurhajec et al.
PloS one, 10(6), e0129868-e0129868 (2015-06-20)
In Hepatitis C virus (HCV) mono-infection, male sex is associated with faster liver fibrosis progression but the effects of sex have not been well studied in HIV-HCV co-infected patients. We examined the influence of sex on progression to significant liver
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