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Merck
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文件

417602

Sigma-Aldrich

2-氯乙基苯基硫醚

98%

别名:

2-(苯硫基)氯乙烷

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About This Item

线性分子式:
ClCH2CH2SC6H5
CAS号:
5535-49-9
分子量:
172.68
Beilstein:
1907116
EC號碼:
226-891-8
MDL號碼:
MFCD00013691
分類程式碼代碼:
12352100
PubChem物質ID:
24866164
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.583 (lit.)

bp

90-91 °C/1 mmHg (lit.)

密度

1.174 g/mL at 25 °C (lit.)

SMILES 字串

ClCCSc1ccccc1

InChI

1S/C8H9ClS/c9-6-7-10-8-4-2-1-3-5-8/h1-5H,6-7H2

InChI 密鑰

QDXIHHOPZFCEAP-UHFFFAOYSA-N

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相关类别

一般說明

2-氯乙基苯硫醚已被报道为硫芥模拟物。它是一种化学战剂（CWA）模拟剂，已经报道了使用氢乙烷膜进行氧化。还报道了它作为化学战剂芥菜[双（2-氯乙基）硫化物]的模拟剂。它在pH 9.0的硼酸盐缓冲液中与囊泡官能化双链表面活性剂（O, O′-二十二烷基磷酸二硫代酸钾）反应，得到[S-[（（2-苯基硫代）乙基]O,O′-二十二烷基磷酸二硫代酸酯]。用[MnL](ClO4)2（L = N,N′,N″-三（2-羟丙基）-1，4，7-三氮杂环壬烷）催化其被H2O2氧化，得到2-氯乙基苯基砜和苯基乙烯基砜。

應用

2-氯乙基苯硫醚是一种硫芥试剂兴奋剂，可以用作生物检定中检测芥子试剂的目标分析物。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Carc. 1A - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

219.2 °F - closed cup

閃點（°C）

104 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Sigma-Aldrich

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In this work a novel bioassay for mustard agent detection was proposed. The bioassay is based on the capability of these compounds to inhibit the enzyme choline oxidase. The enzymatic activity, which is correlated to the mustard agents, was electrochemically
Raymond T Gephart et al.
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Using reactive singlet oxygen (1O2), the oxidation of chemical-warfare agent (CWA) simulants has been demonstrated. The zinc octaphenoxyphthalocyanine (ZnOPPc) complex was demonstrated to be an efficient photosensitizer for converting molecular oxygen (O2) to 1O2 using broad-spectrum light (450-800 nm) from
Reaction of a vesicular functionalized surfactant with 2-chloroethyl phenyl sulfide, a mustard simulant.
Jaeger DA, et al.
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Quaternary ammonium O, O'-dialkylphosphorodithioate surfactants and their reactions with 2-chloroethyl phenyl sulfide, a mustard simulant.
Jaeger DA, et al.
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 196(2), 209-216 (2002)
Sulfide oxidation with H2O2 catalyzed by manganese complex of N,N',N?-tris(2-hydroxypropyl)-1, 4, 7-triazacyclononane.
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