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化驗
99.95% trace metals basis
形狀
evaporation slug
電阻係數
9.96 μΩ-cm, 20°C
直徑×長度
0.6 cm × 0.6 cm
重量
2.4 g (one slug)
bp
2970 °C (lit.)
mp
1554 °C (lit.)
密度
12.02 g/cm3 (lit.)
SMILES 字串
[Pd]
InChI
1S/Pd
InChI 密鑰
KDLHZDBZIXYQEI-UHFFFAOYSA-N
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儲存類別代碼
13 - Non Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Organic & biomolecular chemistry, 11(16), 2574-2577 (2013-03-15)
A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.
The Journal of organic chemistry, 78(8), 4202-4206 (2013-04-03)
Racemic 4-hydroxycyclopentenone, readily derived from furfuryl alcohol, can be transformed via its O-Boc derivative to 4-acyloxy, 4-aryloxy-, 4-amino-, or 4-thio-substituted cyclopentenones with high enantioselectivity by palladium-catalyzed kinetic resolution via nucleophilic allylic substitutions. Applying this methodology, a short formal synthesis of
Water science and technology : a journal of the International Association on Water Pollution Research, 67(8), 1873-1879 (2013-04-13)
A Pd/C gas-diffusion cathode which generated H2O2 through a two-electron reduction process of fed oxygen molecule was used to degrade 4-chlorophenol in an undivided electrolysis device. The kinetics of 4-chlorophenol degradation has been investigated by the electrochemical oxidation processes. By
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