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Merck

371963

Sigma-Aldrich

六氟丙烯三聚体

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About This Item

线性分子式:
[CF3C(F)=CF2]3
CAS号:
分子量:
450.07
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

bp

110-115 °C (lit.)

密度

1.83 g/mL at 25 °C (lit.)

SMILES 字串

FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F.FC(F)=C(F)C(F)(F)F

InChI

1S/3C3F6/c3*4-1(2(5)6)3(7,8)9

InChI 密鑰

VJRSWIKVCUMTFK-UHFFFAOYSA-N

一般說明

Spectra of three isomeric trimers of hexafluoropropene have been investigated. It reacts with primary amines, via indirect substitution of fluorine atoms, to form the corresponding enamines and enimines.

應用

Hexafluoropropene, trimer may be used in the preparation of photochromic spiroindolinonaphthoxazine derivative. It may be used in the preparation of 2-trifluoromethyl-3-heptadifluoroisopropyl-2-perfluoropentene-4-(N′,N′-dimethylamino propyl) imino(I).

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

75.2 °F - closed cup

閃點(°C)

24 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Interaction of hexafluoropropene trimers with ammonia and primary amines.
Del'tsova DP, et al.
Journal of Fluorine Chemistry, 79(1), 97-102 (1996)
Synthesis and NMR study of 9'-substituted spiroindolinonaphthoxazine derivatives.
Kakishita T, et al.
Journal of Heterocyclic Chemistry, 29(7), 1709-1715 (1992)
Non-bond F? F nuclear spin couplings II. Hexafluoropropene trimers.
Cavagna F and Schumann C.
Journal of Magnetic Resonance, 22(2), 333-334 (1969)
D Findik et al.
Journal of cellular biochemistry, 57(1), 12-21 (1995-01-01)
In addition to a role for de novo protein synthesis in apoptosis we have previously shown that activation of a protein phosphatase or loss of activity of a kinase is also important in radiation-induced apoptosis in human cells [Baxter, and
Jost Leemhuis et al.
The Journal of pharmacology and experimental therapeutics, 300(3), 1000-1007 (2002-02-28)
The small GTPase RhoA can retract cell extensions by acting on two Rho kinases (ROCKs). Activated protein kinase A (PKA) inhibits RhoA and induces extensions. The isoquinoline H89 inhibits PKA and thus should prevent the inactivation of RhoA. In kinase

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