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Merck
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文件

28623

Sigma-Aldrich

4-(十七氟辛基)苯胺

≥95.0% (GC)

别名:

4-全氟辛基苯胺

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About This Item

经验公式（希尔记法）:
C14H6F17N
CAS号:
83766-52-3
分子量:
511.18
MDL號碼:
MFCD28134623
分類程式碼代碼:
12352100
PubChem物質ID:
57648316
NACRES:
NA.22

化驗

≥95.0% (GC)

形狀

solid

mp

42-47 °C

SMILES 字串

NC1=CC=C(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(C(F)(F)F)F)F)F)F)F)F)F)C=C1

InChI

1S/C14H6F17N/c15-7(16,5-1-3-6(32)4-2-5)8(17,18)9(19,20)10(21,22)11(23,24)12(25,26)13(27,28)14(29,30)31/h1-4H,32H2

InChI 密鑰

ZQTZVMUNYIDMJV-UHFFFAOYSA-N

相关类别

應用

4-(Heptadecafluorooctyl)aniline was used in the synthesis of fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst.

其他說明

用于引入 4-全氟烷基芳基部分的结构单元

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Lact. - Repr. 1B - STOT RE 1

標靶器官

Liver

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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M. Matsui et al.
Liq. Cryst., 21, 669-669 (1996)
D. Crich et al.
Tetrahedron, 55, 14261-14261 (1999)
N. Yoshino et al.
Bulletin of the Chemical Society of Japan, 65, 2141-2141 (1992)
Liang Wang et al.
Synlett : accounts and rapid communications in synthetic organic chemistry, 3(2010), 433-436 (2010-08-19)
A novel fluorous (S)-pyrrolidine-thiourea bifunctional organocatalyst is prepared. The catalyst shows good activity and enantioselectivity for direct α-chlorination of aldehydes using N-chlorosuccinimide (NCS) as the chlorine source. It can be recovered from the reaction mixture by fluorous solid-phase extraction with

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