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Merck
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文件

283673

Sigma-Aldrich

三氟甲磺酸铜 (II)

98%

别名:

Cu(OTf)2, 三氟甲烷磺酸铜, 三氟甲磺酸 铜(II) 盐, 三氟甲磺酸铜

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About This Item

线性分子式:
(CF3SO3)2Cu
CAS号:
34946-82-2
分子量:
361.68
Beilstein:
4028198
EC號碼:
252-300-8
MDL號碼:
MFCD00077492
分類程式碼代碼:
12161600
PubChem物質ID:
24857124
NACRES:
NA.22

化驗

98%

反應適用性

core: copper
reagent type: catalyst

mp

≥300 °C

SMILES 字串

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI 密鑰

SBTSVTLGWRLWOD-UHFFFAOYSA-L

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相关类别

應用

可用作以下反应的催化剂：
  • 曼尼希缩合反应
  • 环状氨基化
  • Friedel-Crafts反应
  • Henry反应
  • 高价碘试剂介导的咔唑制备
  • 分子内氧化C-N键形成以合成咔唑
有效催化三甲基氰硅烷加成为羰基化合物。

相關產品

产品编号
说明
价格

909424

Cu(OTs)2, ≥95%

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Ahmed M Senan et al.
Journal of agricultural and food chemistry, 65(32), 6912-6918 (2017-07-19)
Utilization of renewable biomass to partly replace the fossil resources in industrial applications has attracted attention due to the limited fossil feedstock with the increased environmental concerns. This work introduced a modified Wacker-type oxidation for transformation of unsaturated fatty acids/esters
Dario Formenti et al.
Chemical reviews, 119(4), 2611-2680 (2018-12-06)
The reduction of nitro compounds to the corresponding amines is one of the most utilized catalytic processes in the fine and bulk chemical industry. The latest development of catalysts with cheap metals like Fe, Co, Ni, and Cu has led
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
Biswarup Chakraborty et al.
Chemistry, an Asian journal, 15(6), 852-859 (2020-02-06)
In the urge of designing noble metal-free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 CuI (PyHS)}2 ](OTf)2 (1), and utilized as an anode material
Nicole W G Smits et al.
Inorganic chemistry, 58(19), 13007-13019 (2019-09-25)
The structure of the copper complex of the 6-((1-butanethiol)oxy)-tris(2-pyridylmethyl)amine ligand (Cu-tmpa-O(CH2)4SH) anchored to a gold surface has been investigated. To enable covalent attachment of the complex to the gold surface, a heteromolecular self-assembled monolayer (SAM) of butanethiol and a thiol-substituted
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