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Merck
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文件

279617

Sigma-Aldrich

2-苯基-1,3-二噻烷

97%

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About This Item

经验公式（希尔记法）:
C10H12S2
CAS号:
5425-44-5
分子量:
196.33
EC號碼:
226-568-1
MDL號碼:
MFCD00006656
分類程式碼代碼:
12352100
PubChem物質ID:
24856897

化驗

97%

形狀

solid

mp

72-74 °C (lit.)

溶解度

acetone: soluble 25 mg/mL, clear, colorless to yellow

SMILES 字串

C1CSC(SC1)c2ccccc2

InChI

1S/C10H12S2/c1-2-5-9(6-3-1)10-11-7-4-8-12-10/h1-3,5-6,10H,4,7-8H2

InChI 密鑰

GXKPARDRBFURON-UHFFFAOYSA-N

一般說明

The full set of NMR spectral parameters (1H, 13C, 31P) for 2-phenyl-1,3-dithiane has been reported.

應用

2-Phenyl-1,3-dithiane is a versatile acyl anion equivalent and has been used in the preparation of benzaldehyde-1-d.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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Synthesis of 1-deuterioaldehydes. Benzaldehyde-1-D.
Seebach D, et al.
The Journal of Organic Chemistry, 31(12), 4303-4304 (1966)
NMR spectral analysis of 1, 3, 2-dithiaphosphorinanes and 1, 3-dithianes.
Martin J and Robert JB.
Org. Magn. Reson., 7(2), 76-77 (1975)
Smith, A. B., III; Boldi, A. M.
Journal of the American Chemical Society, 119, 6925-6925 (1997)
Amos B Smith et al.
Journal of the American Chemical Society, 125(47), 14435-14445 (2003-11-20)
The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading to the rapid, efficient, and stereocontrolled assembly of highly functionalized intermediates for complex molecule synthesis

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