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Merck

260924

Sigma-Aldrich

双(环戊二烯)二氯化铌(IV)

95%

别名:

二(环戊二烯基)二氯化铌(IV), 二氯二茂铌

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About This Item

经验公式(希尔记法):
C10H10Cl2Nb
CAS号:
分子量:
294.00
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22

化驗

95%

反應適用性

core: niobium
reagent type: catalyst

SMILES 字串

Cl[Nb]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Nb/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI 密鑰

CYMWZQTUXXEBCR-UHFFFAOYSA-L

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應用

Catalyst for:
  • Chain growth in controlled polymerization reactions
  • Reduction elimination reactions
  • Olefin polymerization reactions

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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M M Harding et al.
Journal of medicinal chemistry, 39(25), 5012-5016 (1996-12-06)
The solution chemistry and interactions of niobocene dichloride, Cp2NbCl2, with nucleosides, nucleotides, and amino acids has been studied by 1H and 31P NMR spectroscopy. The 1H NMR spectrum of Cp2NbCl2 in 10% DMSO-d6/D2O contains two sharp singlets consistent with hydrolysis
G Mokdsi et al.
Journal of inorganic biochemistry, 86(2-3), 611-616 (2001-09-22)
The interaction of the antitumor active metallocene dihalides Cp(2)MCl(2) (M=Ti, Nb, Mo) and 1 equiv. of glutathione was studied by (1)H NMR spectroscopy at pD 2-7 in 4 mM NaCl solutions. No interaction between glutathione and titanocene dichloride was detected

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