方案
≥97.0%
表单
solid
沸点
109-111 °C/0.01 mmHg
mp
33-35 °C
储存温度
−20°C
SMILES字符串
ClCS(=O)c1ccccc1
InChI
1S/C7H7ClOS/c8-6-10(9)7-4-2-1-3-5-7/h1-5H,6H2
InChI key
WCUSVVDFUIMPKY-UHFFFAOYSA-N
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一般描述
Chloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated.
应用
Chloromethyl phenyl sulfoxide has been used in the preparation of:
- 1-chloroalkyl sulfoxides
- starting material for the synthesis alkyl sulfoxides and thiol ester acyl anion equivalent
其他说明
合成烷基亚砜的原料；硫羟酸酯的酰基阴离子等价物
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide.
Durst T.
Journal of the American Chemical Society, 91(4), 1034-1035 (1969)
Tsuyoshi Satoh
Chemical record (New York, N.Y.), 3(6), 329-341 (2004-03-03)
Aryl 1-chlorovinyl sulfoxides were easily synthesized from ketones and aldehydes with aryl chloromethyl sulfoxide in three-steps with high overall yields. Low-temperature treatment of the aryl 1-chlorovinyl sulfoxides with alkyllithium or a Grignard reagent gave alkylidene carbenoids via a sulfoxide-metal exchange
K.M. Moore et al.
The Journal of Organic Chemistry, 43, 2713-2713 (1978)
M. Hojo et al.
Synthesis, 789-789 (1977)
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