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Merck
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23030

Sigma-Aldrich

1-氯乙基碳酸乙酯

≥98.0% (GC)

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About This Item

线性分子式:
CH3CH2OCOOCHClCH3
CAS号:
50893-36-2
分子量:
152.58
Beilstein:
3536477
EC 号:
256-832-1
MDL编号:
MFCD00040523
UNSPSC代码:
12352100
PubChem化学物质编号:
57648014
NACRES:
NA.22

方案

≥98.0% (GC)

折射率

n20/D 1.413

沸点

159-161 °C (lit.)

密度

1.136 g/mL at 20 °C (lit.)

储存温度

2-8°C

SMILES字符串

CCOC(=O)OC(C)Cl

InChI

1S/C5H9ClO3/c1-3-8-5(7)9-4(2)6/h4H,3H2,1-2H3

InChI key

YVRGKFXJZCTTRB-UHFFFAOYSA-N

其他说明

基团保护试剂，可在酸、苯酚和胺上引入酸裂解基团 1-(乙氧基羰基氧基)乙基；在制药上，1-(乙氧基羰基氧基)乙基衍生物作为掩蔽产物，可在血浆中水解

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

149.0 °F - closed cup

闪点(°C)

65 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCBZ8256
BCBS3297V

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C M Svahn et al.
Journal of medicinal chemistry, 29(4), 448-453 (1986-04-01)
Derivatives of the antifibrinolytic drug tranexamic acid [trans-4-(aminomethyl)cyclohexanecarboxylic acid] containing one or two tranexamic acid moieties were synthesized. Most of the derivatives have good stability in acidic and neutral solutions but are easily hydrolyzed in plasma. By measuring the amount
T Nishimura et al.
The Journal of antibiotics, 40(1), 81-90 (1987-01-01)
Orally active 1-(alkyl substituted cyclohexyloxycarbonyloxy)alkyl ester prodrugs (9b-h) of 7 beta-[2-(2-aminothiazol-4-yl)acetamido]-3- [[[1-(2-dimethylaminoethyl)-1H-tetrazol-5-yl]thio]-methyl]ceph+ ++-3- em-4-carboxylic acid (cefotiam, CTM) have been studied as well as the thia (9i) and aza (9j) analogs. These represent derivatives of the 1-(cyclohexylacetoxy)ethyl ester (2) of CTM.
G. Barcelo et al.
Synthesis, 627-627 (1986)
Tigist Y Tamir et al.
Journal of cell science, 133(14) (2020-06-18)
Nuclear factor erythroid 2-related factor 2 (NFE2L2, also known as NRF2) is a transcription factor and master regulator of cellular antioxidant response. Aberrantly high NRF2-dependent transcription is recurrent in human cancer, but conversely NRF2 activity diminishes with age and in
Caiyun G Li et al.
Cell reports, 26(5), 1333-1343 (2019-01-31)
Using proteomic approaches, we uncovered a DNA damage response (DDR) function for peroxisome proliferator activated receptor γ (PPARγ) through its interaction with the DNA damage sensor MRE11-RAD50-NBS1 (MRN) and the E3 ubiquitin ligase UBR5. We show that PPARγ promotes ATM
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