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Merck

221678

Sigma-Aldrich

Raney®-镍

W.R. Grace and Co. Raney® 2800, slurry, in H2O, active catalyst

别名:

雷尼镍, 海绵镍

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About This Item

线性分子式:
AlNi
CAS号:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

形狀

slurry

成份

Ni, ≥89%

反應適用性

core: nickel
reagent type: catalyst

製造商/商標名

W.R. Grace and Co. Raney® 2800

濃度

in H2O

雜質

6-9% Al

粒徑

20-60 μm

pH值

8.5-12.0

SMILES 字串

[Al].[Ni]

InChI

1S/Al.Ni

InChI 密鑰

NPXOKRUENSOPAO-UHFFFAOYSA-N

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應用

用作有机化合物氢化作用的还原剂,如腈氢化成胺、芳基还原成相应的饱和化合物、β-酮酸酯加氢反应、还原胺化,还用于羟吲哚与醇的3-烷基化反应、Ullman型交叉偶联反应和脱卤反应。
适于用作芳基、烯基、氰基和硝基还原的加氢催化剂。

法律資訊

Raney is a registered trademark of W.R. Grace & Co.-Conn.

訊號詞

Danger

危險分類

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Michał Sarul et al.
Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 22(2), 253-260 (2013-05-28)
Cognizance of the mechanical properties of nickel-titanium archwires is necessary for the management of orthodontic therapy with fixed appliances. Acting on the periodontium with forces that are too heavy may lead to such complications as: pain, tooth root resorption and
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)
Fariborz Amini et al.
International journal of orthodontics (Milwaukee, Wis.), 24(1), 43-44 (2013-06-05)
In this report, we present an uncomplicated approach to overcome lingual rolling of mandibular molars during orthodontic treatment, by using rectangular NiTi arch wire in twist fashion through the molar tube. The sequential steps of the twist manoeuvre on a
Picture of the month. Allergic contact dermatitis to nickel-containing dental work.
Emma F Johnson et al.
JAMA pediatrics, 167(6), 581-582 (2013-06-05)

商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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