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蒸汽壓力
29.72 psi ( 55 °C)
9.05 psi ( 20 °C)
品質等級
形狀
liquid
反應適用性
core: boron
reagent type: Lewis acid
reagent type: catalyst
濃度
1.0 M in methylene chloride
密度
1.326 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
ClB(Cl)Cl
InChI
1S/BCl3/c2-1(3)4
InChI 密鑰
FAQYAMRNWDIXMY-UHFFFAOYSA-N
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一般說明
Boron trichloride is a boron halide. It participates in the hydroboration of alkenes. It forms strongly polarized donor-acceptor complexes with trimethyl- and triethylsilyl triflate. Boron trichloride assisted reaction between acid chlorides and alkynyltrifluoroborate salts have been reported to form ynones.
Boron trichloride solution is used as a Lewis acid catalyst in the synthesis of BN-phenanthrenes.
Boron trichloride solution is used as a Lewis acid catalyst in the synthesis of BN-phenanthrenes.
應用
Boron trichloride may be used in the synthesis of Cl-BODIPYs (BODIPY - Boron-dipyrromethene) and tris(dimethylamino)borane. It may be used in the synthesis of sceptrins and nakamuric acid.
用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。
包裝
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Carc. 2 - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - STOT SE 3
標靶器官
Central nervous system
儲存類別代碼
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hydroboration with boron halides and trialkylsilanes.
Soundararajan R and Matteson DS.
The Journal of Organic Chemistry, 55(8), 2274-2275 (1990)
Organometallic chemistry. 21. Silyl trifluoromethanesulfonate (triflate)-boron trichloride (tribromide) complexes.
Olah GA, et al.
Organometallics, 3(9), 1337-1340 (1984)
Synthesis of highly electrically conductive and electrochemically stable porous boron-doped carbon microspheres
Bose, Anima B and Yang, et al.
SN Applied Sciences, 1, 1-8 (2019)
A New Member of the BN-Phenanthrene Family: Understanding the Role of the B?N Bond Position
Abengo?zar, Alberto and Sucunza
The Journal of Organic Chemistry, 84, 7113-7122 (2019)
Xiaolei Wang et al.
Organic chemistry frontiers : an international journal of organic chemistry, 2(8), 978-984 (2015-09-04)
Sceptrins and nakamuric acid are structurally unique antibiotics isolated from marine sponges. Recent studies suggest that the biosynthesis of these dimeric pyrrole-imidazole alkaloids involves a single-electron transfer (SET)-promoted [2+2] cycloaddition to form their cyclobutane core skeletons. We describe herein the
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