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化驗
98%
形狀
liquid
折射率
n20/D 1.489 (lit.)
bp
87-88 °C/7 mmHg (lit.)
密度
1.061 g/mL at 25 °C (lit.)
SMILES 字串
COC(OC)(OC)c1ccccc1
InChI
1S/C10H14O3/c1-11-10(12-2,13-3)9-7-5-4-6-8-9/h4-8H,1-3H3
InChI 密鑰
IECKAVQTURBPON-UHFFFAOYSA-N
一般說明
原苯甲酸三甲酯与对二甲基氨基膦酸双(1-甲基肼)反应生成 1,2,5,6-四氢-1,5-二甲基-6-(N,N-二甲基氨基)-6-苯基-1,2,4,5,6-四氮杂膦-6-氧化物。
應用
原苯甲酸三甲酯用于制备 1-苯基-硫代-α-L-鼠李糖吡喃糖苷的 5-苯基-4,6-二吡啶和 2,3-原酸酯衍生物。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
179.6 °F - closed cup
閃點(°C)
82 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Incidence and avoidance of stereospecific 1, 2-ethylthio group migration during the synthesis of ethyl 1-thio-a-l-rhamnopyranoside 2, 3-orthoester.
Carbohydrate Research, 212, 13-24 (1991)
Inorganic chemistry, 40(8), 1865-1870 (2001-04-21)
Reaction of P-dimethylaminophosphonic acid bis(1-methylhydrazide) (6) with trimethyl orthobenzoate gave 1,2,5,6-tetrahydro-1,5-dimethyl-6-(N,N-dimethylamino)-6-phenyl-1,2,4,5,6-tetrazaphosphorine-6-oxide (7), which was subsequently oxidized to the corresponding P-diemthylamino-6-phosphaverdazyl (5) as a persistent radical. Analysis of the electron paramagnetic resonance spectrum of 5 revealed significant spin density on the
Reactions between pyrrole and orthoesters: preparation of tri-(pyrrol-2-yl) alkanes.
Tetrahedron Letters, 43(32), 5545-5547 (2001)
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