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质量水平
方案
95%
表单
liquid
折射率
n20/D 1.443 (lit.)
沸点
107-110 °C/11 mmHg (lit.)
密度
1.063 g/mL at 25 °C (lit.)
官能团
ester
储存温度
2-8°C
SMILES字符串
CCOC(=O)C#CC(=O)OCC
InChI
1S/C8H10O4/c1-3-11-7(9)5-6-8(10)12-4-2/h3-4H2,1-2H3
InChI key
STRNXFOUBFLVIN-UHFFFAOYSA-N
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一般描述
丁炔二酸二乙酯是一种蛋白交联剂。
丁炔二酸二乙酯可用于O-乙烯基肟合成的Michael受体，并用于亲核加成反应。
丁炔二酸二乙酯可用于O-乙烯基肟合成的Michael受体，并用于亲核加成反应。
应用
丁炔二酸二乙酯被用于合成：
- 3,4,5-三取代2(5H)-呋喃酮衍生物
- 高度官能化的噻唑烷酮衍生物
- 新型环状过氧化物葡萄糖苷
- 通过Diels-Alder反应合成4,11-dimesitylbisanthene，一种可溶性bisanthene衍生物
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
201.2 °F - closed cup
闪点(°C)
94 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Abdelmadjid Benmohammed et al.
Molecules (Basel, Switzerland), 19(3), 3068-3083 (2014-03-13)
We present herein the synthesis in good yields of two series of highly functionalized thiazolidinone derivatives from the reactions of various 4-phenyl-3-thio-semicarbazones with ethyl 2-bromoacetate and diethyl acetylenedicarboxylate, respectively.
Microwave Induced Stereoselective Synthesis of O--Vinyl Oximes using Acetylenic Esters as Efficient Michael Acceptors
Ankush M et al.
ChemistrySelect, 3, 9464-9468 (2018)
Eric H Fort et al.
Journal of the American Chemical Society, 131(44), 16006-16007 (2009-10-17)
A soluble bisanthene derivative, 4,11-dimesitylbisanthene, has been synthesized in three steps from bianthrone. In hot toluene, this bisanthene undergoes a clean Diels-Alder reaction with diethyl acetylenedicarboxylate to give a rearomatized 1:1 cycloadduct and, more slowly, a rearomatized 2:1 cycloadduct. In
Di-Zao Li et al.
Journal of Asian natural products research, 11(7), 613-620 (2010-02-26)
Four novel cyclic peroxide glucosides 15a, 15b, 16a, and 16b, optically pure analogs of shuangkangsu (1), which is an anti-virus natural product with an unusual skeleton isolated from the buds of Lonicera japonica Thunb, were first synthesized totally in six
Synthesis of pyrrolidinone derivatives from aniline, an aldehyde and diethyl acetylenedicarboxylate in an ethanolic citric acid solution under ultrasound irradiation
Hamideh A et al.
Green Chemistry, 18, 3582-3593 (2016)
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