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Merck

157333

Sigma-Aldrich

3-氯苯甲醚

98%

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About This Item

线性分子式:
ClC6H4OCH3
CAS号:
分子量:
142.58
Beilstein:
2041497
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.536 (lit.)

bp

193 °C (lit.)

密度

1.164 g/mL at 25 °C (lit.)

SMILES 字串

COc1cccc(Cl)c1

InChI

1S/C7H7ClO/c1-9-7-4-2-3-6(8)5-7/h2-5H,1H3

InChI 密鑰

YUKILTJWFRTXGB-UHFFFAOYSA-N

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一般說明

One-step preparation of 3-chloroanisole from the corresponding 3-substituted nitrobenzene has been reported.

應用

3-Chloroanisole was employed as starting reagent in the regioselective synthesis of 4- and 7-alkoxyindoles. It was also employed as electrolyte additive for the overcharging protection of Li-ion cell.

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

163.4 °F - closed cup

閃點(°C)

73 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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One-step preparation of some 3-substituted anisoles.
Zilberman J.
Organic Process Research & Development, 7(3), 303-305 (2003)
Roberto Sanz et al.
The Journal of organic chemistry, 72(14), 5113-5118 (2007-06-15)
An efficient and regioselective synthesis of 4- and 7-alkoxyindoles has been developed from commercially available starting materials such as 3-halophenols and 3-chloroanisole. Directed ortho-metalation followed by two palladium-catalyzed processes, a Sonogashira coupling and a tandem amination/cyclization reaction, allows the synthesis
3-Chloroanisole for overcharge protection of a Li-ion cell.
Lee Y-G and Cho J.
Electrochimica Acta, 52(25), 7404-7408 (2007)

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