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75920

Sigma-Aldrich

OXONE® tetrabutylammonium salt

technical, ~1.6% active oxygen basis

Synonym(s):

Tetrabutylammonium OXONE®, Tetrabutylammonium hydrogen monopersulfate, Tetrabutylammonium peroxomonosulfate, Tetrabutylammonium persulfate triple salt

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25 G
$340.00
100 G
$1,160.00

$340.00

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25 G
$340.00
100 G
$1,160.00

About This Item

CAS Number:
104548-30-3
Beilstein:
5199887
MDL number:
MFCD20503057
UNSPSC Code:
12352000
PubChem Substance ID:
24886893
NACRES:
NA.22
form:
powder

$340.00

Please contact Customer Service for Availability
Request a Bulk Order

Quality Level

100

grade

technical

form

powder

reaction suitability

reagent type: oxidant

concentration

~1.6% (active oxygen)

mp

144-146 °C

SMILES string

OS([O-])(=O)=O.[O-]S([O-])(=O)=O.OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC

InChI

1S/5C16H36N.2H2O5S.2H2O4S/c5*1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2*1-5-6(2,3)4;2*1-5(2,3)4/h5*5-16H2,1-4H3;2*1H,(H,2,3,4);2*(H2,1,2,3,4)/q5*+1;;;;/p-5

InChI key

IGMBKNUVZFAHJM-UHFFFAOYSA-I

Application

Reagent for:
  • Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexes
  • Epoxidation of alkenes
  • Oxidation of sulfides and olefins
  • Oxidation of alcohols
  • Oxidation of aromatic amines for synthesis of azoxy arenes

Other Notes

Form of Oxone specially suited for the oxidation of sensitive compounds in CH2Cl2[1][2][3]; Reagent for preparing 2-tetrahydrofuranyl ethers from alcohols and THF by radical coupling[4]

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Pictograms

CorrosionExclamation mark
GHS05,GHS07

Signal Word

Danger

Hazard Statements

H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG6320
BCBX3972
BCBL8047V
BCBF0794V
1382891V

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J.C. Jung et al.
Tetrahedron Letters, 34, 3581-3581 (1993)
B.M. Trost et al.
The Journal of Organic Chemistry, 53, 532-532 (1988)
R. Cosstick et al.
Tetrahedron Letters, 30, 4693-4693 (1989)
R. Annunziata et al.
The Journal of Organic Chemistry, 55, 1901-1901 (1990)

Questions

  1. Greetings, I would like to inquire about this compound's solubility profile (CAS Number: 104548-30-3). I would like to know if it dissolves in organic solvents.

    1 answer

    1. 75920 is OXONE tetrabutylammonium salt that is soluble in dichloromethane. However, no information on saturation concentration is available.

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