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Chemistry (Weinheim an der Bergstrasse, Germany), 18(31), 9564-9570 (2012-07-07)
Ammoniomethyl trifluoroborates are very powerful reagents that can be used to access biologically relevant aryl- and heteroaryl-methylamine motifs via Suzuki-Miyaura cross-couplings. Until now, this method was limited to the production of tertiary and primary amines. The synthesis of a large
Prikladnaia biokhimiia i mikrobiologiia, 48(6), 606-611 (2013-01-22)
Methanol dehydrogenase (MDG) of the facultative methylotrophic phytosymbiont Methylobacterium nodulans has been purified for the first time to an electrophoretically homogeneous state and characterized. The native protein with a molecular mass of 70 kDa consists of large (60 kDa) and
The journal of physical chemistry. B, 116(51), 14788-14804 (2012-11-23)
We study the initial steps of the interaction of water molecules with two unsolvated peptides: Ac-Ala(5)-LysH(+) and Ac-Ala(8)-LysH(+). Each peptide has two primary candidate sites for water adsorption near the C-terminus: a protonated carboxyl group and the protonated ammonium group
The journal of physical chemistry. B, 117(1), 316-325 (2012-12-15)
Proton-coupled electron transfer can occur through concerted (electron-proton transfer, EPT) or sequential mechanisms, but this distinction becomes less well-defined for photoinduced reactions. These issues have been examined with transient absorption experiments on a hydrogen-bonded complex consisting of p-nitrophenylphenol and t-butylamine.
Physical chemistry chemical physics : PCCP, 15(13), 4707-4714 (2013-02-21)
Using density functional theory calculations, we report on the adsorption of methylamine on gold and compare its adsorption to a selection of alkylamines, methanol and methanethiol. On the (111) surface, the amines, thiol and alcohol bind in the ontop site
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