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About This Item
Empirical Formula (Hill Notation):
C7H16S2Si
CAS Number:
Molecular Weight:
192.42
Beilstein:
1616463
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Assay
≥99%
refractive index
n20/D 1.533 (lit.)
bp
54-55 °C/0.17 mmHg (lit.)
density
1.014 g/mL at 25 °C (lit.)
functional group
thioether
SMILES string
C[Si](C)(C)C1SCCCS1
InChI
1S/C7H16S2Si/c1-10(2,3)7-8-5-4-6-9-7/h7H,4-6H2,1-3H3
InChI key
BTTUMVHWIAXYPJ-UHFFFAOYSA-N
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General description
2-(Trimethylsilyl)-1,3-dithiane participates in Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines. It undergoes novel diazo transfer reaction with tosyl azide in hexamethylphosphoramide-THF to yield 2-diazo-1,3-dithiane, which on decomposition yields formal carbene adducts. It is a versatile acyl anion equivalent.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
204.8 °F - closed cup
Flash Point(C)
96 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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