157279
Ethyl 2-formyl-1-cyclopropanecarboxylate, predominantly trans
96%
Sign Into View Organizational & Contract Pricing
All Photos(2)
About This Item
Linear Formula:
HCOC3H4CO2C2H5
CAS Number:
Molecular Weight:
142.15
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
96%
form
liquid
refractive index
n20/D 1.452 (lit.)
bp
60-65 °C/0.6 mmHg (lit.)
density
1.074 g/mL at 25 °C (lit.)
functional group
aldehyde
ester
storage temp.
2-8°C
SMILES string
CCOC(=O)C1CC1C=O
InChI
1S/C7H10O3/c1-2-10-7(9)6-3-5(6)4-8/h4-6H,2-3H2,1H3
InChI key
MDWXTLNIZCHBJE-UHFFFAOYSA-N
General description
Ethyl 2-formyl-1-cyclopropanecarboxylate was formed by acid catalyzed reaction between acrolein and ethyl diazoacetate.
Application
Ethyl 2-formyl-1-cyclopropanecarboxylate was used in the preparation of ethyl trans-2-(4-(methylphenyl)sulfonyl-4,5-dihydrooxazol-5-yl)cyclopropanecarboxylate.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
183.2 °F - closed cup
Flash Point(C)
84 °C - closed cup
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Acid catalyzed reactions of a, ?-unsaturated aldehydes and ethyl diazoacetate.
Branstetter B and Hossain MM.
Tetrahedron Letters, 47(2), 221-223 (2006)
I J De Esch et al.
Journal of medicinal chemistry, 42(7), 1115-1122 (1999-04-10)
Various approaches to the synthesis of all four stereoisomers of 2-(1H-imidazol-4-yl)cyclopropylamine (cyclopropylhistamine) are described. The rapid and convenient synthesis and resolution of trans-cyclopropylhistamine is reported. The absolute configuration of its enantiomers was determined by single-crystal X-ray crystallographic analysis. The distinct
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service