253049
Potash, sulfurated
Synonym(s):
Dipotassium thiosulfate mixture with potassium sulfide, Liver of sulfur, Sulfurated potash
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About This Item
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form
chunks
lumps
Quality Level
composition
sulfide, ≥12.8%
SMILES string
[K+].[K+].[K]S[K].[O-]S([O-])(=O)=S
InChI
1S/4K.H2O3S2.S/c;;;;1-5(2,3)4;/h;;;;(H2,1,2,3,4);/q;;2*+1;;/p-2
InChI key
PFSBHPPVZHPSCB-UHFFFAOYSA-L
Application
Sulfurated potash may be used in the preparation of N-substituted thionamides such as (+)-(S)-thion-α-methylbutyramide, (+)-(S)-(thionhydratropyl)morpholine and (+)-(S)-N-methylthion-α-methylbutyramide.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
Target Organs
Respiratory system
Supplementary Hazards
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Optical Rotatory Dispersion Studies. XCVII. Anomalous Rotatory Dispersion and Circular Dichroism Curves Associated with Thionamides. Application to Stereochemical Studies of Carboxylic Acids2
Journal of the American Chemical Society, 87(1), 51-60 (1965)
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