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02659

Supelco

Tetraethylene glycol dimethyl ether

analytical standard

Synonym(s):

2,5,8,11,14-Pentaoxapentadecane, Bis[2-(2-methoxyethoxy)ethyl] ether, Dimethoxytetraethylene glycol, Dimethyltetraglycol, Tetraglyme

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About This Item

Linear Formula:
CH3O(CH2CH2O)4CH3
CAS Number:
Molecular Weight:
222.28
Beilstein:
1760005
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

7.7 (vs air)

vapor pressure

<0.01 mmHg ( 20 °C)

Assay

≥99.7% (GC)

autoignition temp.

510 °F

shelf life

limited shelf life, expiry date on the label

range of application measuring range

≤60 °C

refractive index

n20/D 1.432 (lit.)
n20/D 1.432

bp

275-276 °C (lit.)

mp

−30 °C (lit.)

density

1.009 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

SMILES string

COCCOCCOCCOCCOC

InChI

1S/C10H22O5/c1-11-3-5-13-7-9-15-10-8-14-6-4-12-2/h3-10H2,1-2H3

InChI key

ZUHZGEOKBKGPSW-UHFFFAOYSA-N

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General description

Tetraethylene glycol dimethyl ether is a non-volatile, higher molecular weight glyme solvent.[1]

Application

Tetraethylene glycol dimethyl ether may be used as an analytical reference standard for the quantification of the analyte in water samples using gas chromatography/mass spectrometry technique.[2]

Pictograms

Health hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Repr. 1B

Supplementary Hazards

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

276.8 °F - closed cup

Flash Point(C)

136 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH SVHC Candidate List

CAS No.

EU REACH Annex XVII (Restriction List)

CAS No.

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Simultaneous determination of six hydrophilic ethers at trace levels using coconut charcoal adsorbent and gas chromatography/mass spectrometry.
Stepien DK and Puttmann W.
Analytical and Bioanalytical Chemistry, 405(5), 1743-1751 (2013)
Stability of superoxide radicals in glyme solvents for non-aqueous Li?O 2 battery electrolytes
Schwenke UK
Physical Chemistry Chemical Physics, 15(28), 11830-11839 (2013)
Lan Cao et al.
Journal of biomedical materials research. Part A, 79(4), 788-803 (2006-08-03)
Previous studies from our lab have shown that fibrinogen adsorption (Gamma(Fg)) must be reduced below 10 ng/cm(2) to significantly reduce platelet adhesion, and that radio frequency glow discharge (RFGD) treatment of polymeric films in the presence of tetraethylene glycol dimethyl
Malinda Salim et al.
Lab on a chip, 7(4), 523-525 (2007-03-29)
This Technical Note presents the direct surface modification of a glass/PTFE hybrid microfluidic chip, via radio frequency glow discharge plasma polymerisation of tetraethlylene glycol dimethylether (tetraglyme), to produce hydrophilic, non-fouling, PEO-like surfaces. We use several techniques including X-ray photoelectron spectroscopy
Claire R Hurley et al.
Langmuir : the ACS journal of surfaces and colloids, 26(12), 10203-10209 (2010-03-25)
Plasma-polymerized tetraglyme films (PP4G) have been modified by exposure to ultraviolet (UV) light from a frequency-doubled argon ion laser (244 nm) and characterized using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). XPS data indicated that the ether component

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