07-3750
Diiodomethane
SAJ first grade, ≥98.0%
Synonym(s):
Methylene iodide
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About This Item
Empirical Formula (Hill Notation):
CH2I2
CAS Number:
Molecular Weight:
267.84
Beilstein:
1696892
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
Pricing and availability is not currently available.
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grade
SAJ first grade
vapor density
9.25 (vs air)
Assay
≥98.0%
form
liquid
availability
available only in Japan
bp
67-69 °C/11 mmHg (lit.)
mp
5-8 °C (lit.)
density
3.325 g/mL at 25 °C (lit.)
SMILES string
ICI
InChI
1S/CH2I2/c2-1-3/h1H2
InChI key
NZZFYRREKKOMAT-UHFFFAOYSA-N
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
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Qingyu Kong et al.
The journal of physical chemistry. A, 109(45), 10451-10458 (2006-07-13)
Various molecular species are known to form during the photoreaction of C2H4I2 in the gas phase and in solution. We have studied all species involved in this reaction by ab initio and density functional theory (DFT) calculations: Geometries, energies, and
H Ihee et al.
Science (New York, N.Y.), 309(5738), 1223-1227 (2005-07-16)
We report direct structural evidence of the bridged radical (CH2ICH2.) in a polar solution, obtained using time-resolved liquid-phase x-ray diffraction. This transient intermediate has long been hypothesized to explain stereo-chemical control in many association and/or dissociation reactions involving haloalkanes. Ultrashort
Eun Chul Cho et al.
Langmuir : the ACS journal of surfaces and colloids, 24(18), 9974-9978 (2008-08-21)
This study presents a method to measure the contact angles of oils on a substrate in water. Diiodomethane and perfluorodecalin were used as model oils. Self-assembled monolayers (SAMs) were prepared by adjusting the mole ratio of CH 3- and OH-terminated
Elodie Velzenberger et al.
Colloids and surfaces. B, Biointerfaces, 68(2), 238-244 (2008-12-26)
Wettability of biomaterials surfaces and protein-coated substrates is generally characterized with the sessile drop technique using polar and apolar liquids. This procedure is often performed in air, which does not reflect the physiological conditions. In this study, liquid/liquid contact angle
Kevin Cheng et al.
Organic letters, 13(9), 2346-2349 (2011-04-06)
A diastereoselective synthesis of trans-2-substituted cyclopropanols is outlined. Bimetallic CH(2)(ZnI)(2) was found to react with α-chloroaldehydes to give cyclopropanols in yields of 64-89% and dr's ≥ 10:1. The high trans-selectivity resulted from equilibration of the cyclopropoxide intermediates.
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