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923443

Sigma-Aldrich

PhMPhos

greener alternative

Synonym(s):

1-Diadamantylphosphino-1′-diphenylphosphinoferrocene

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100 MG
739,00 kr
500 MG
2 220,00 kr

739,00 kr

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100 MG
739,00 kr
500 MG
2 220,00 kr

About This Item

Empirical Formula (Hill Notation):
C42H48FeP2
Molecular Weight:
670.62
UNSPSC Code:
12352200
NACRES:
NA.21

739,00 kr

Please contact Customer Service for Availability
Request a Bulk Order

form

powder

Quality Level

100

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings
reagent type: ligand

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

functional group

phosphine

greener alternative category

Aligned

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp2-Csp3 coupling. Demonstrated Csp2-Csp3 couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR2)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp2–Csp3 Couplings

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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