902063
(2Z,6Z)-N′2,N′6-Dicyanopyridine-2,6-bis(carboximidamide)
Synonym(s):
Weix 2-pyridyl-N-cyanocarboxamidine ligand for nickel catalysis
Sign Into View Organizational & Contract Pricing
All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C9H7N7
CAS Number:
Molecular Weight:
213.20
UNSPSC Code:
12352111
NACRES:
NA.22
Recommended Products
![Mesyl[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)](/deepweb/assets/sigmaaldrich/product/structures/358/298/6539c19e-808c-4cd1-b9e8-19c6928f2384/640/6539c19e-808c-4cd1-b9e8-19c6928f2384.png)
![[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride](/deepweb/assets/sigmaaldrich/product/structures/471/091/6faa29b1-bf8a-4d87-90b2-4cc55e082620/640/6faa29b1-bf8a-4d87-90b2-4cc55e082620.png)
form
powder or crystals
reaction suitability
core: nickel
reaction type: Cross Couplings
reagent type: catalyst
mp
>300 °C
Application
This pyridyl carboxamidine ligand has been demonstrated by Daniel Weix′s lab to enable nickel-catalyzed cross-coupling of diverse basic nitrogen heterocycles with primary and secondary alkyl halides.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Eric C Hansen et al.
The Journal of organic chemistry, 82(14), 7085-7092 (2017-07-07)
Despite their importance, the synthesis of alkylated heterocycles from the cross-coupling of Lewis basic nitrogen heteroaryl halides with alkyl halides remains a challenge. We report here a general solution to this challenge enabled by a new collection of ligands based
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service