449563
Borane diphenylphosphine complex
98%
Synonym(s):
(Diphenylphosphine)trihydroboron
About This Item
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Assay
98%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Reductions
reagent type: reductant
bp
148-150 °C/10 mmHg (lit.)
mp
47-50 °C (lit.)
SMILES string
B.[H]P(c1ccccc1)c2ccccc2
InChI
1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChI key
XUFGOLYVDOBYLK-UHFFFAOYSA-N
Application
- Nucleophilic addition reactions (anion)
- Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
- Deprotonation reactions
- Catalytic coupling with alkynyl bromides
- Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
- Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
- Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Water-react 2
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
Certificates of Analysis (COA)
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