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427128

Sigma-Aldrich

Gallium(III) chloride

anhydrous, beads, ≥99.999% trace metals basis

Synonym(s):

Gallium trichloride

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About This Item

Linear Formula:
GaCl3
CAS Number:
Molecular Weight:
176.08
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

vapor pressure

1 mmHg ( 48 °C)

Assay

≥99.999% trace metals basis

form

beads

reaction suitability

reagent type: catalyst
core: gallium

impurities

≤10.0 ppm Trace Metal Analysis

mp

78 °C (lit.)

density

2.47 g/mL at 25 °C (lit.)

SMILES string

Cl[Ga](Cl)Cl

InChI

1S/3ClH.Ga/h3*1H;/q;;;+3/p-3

InChI key

UPWPDUACHOATKO-UHFFFAOYSA-K

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General description

Gallium(III) chloride is prepared by reacting Ga metal with Cl2 or HCl in N2 at 200oC.1

Application

Catalyst for a number of transformations such as the ring opening and recyclization of epoxides or the trimerization of alkynes.

Features and Benefits

Lower-temperature solvothermal techniques using GaCl3 and NaN3 or Li3N result in nanocrystalline GaN.
Radical mediator and catalyst in a number of organic bond formation reactions.

Packaging

product is packed in vials

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Chien-Hui Syu et al.
The Science of the total environment, 759, 143943-143943 (2020-12-20)
The emerging contaminants gallium (Ga) and indium (In) are extensively used in advanced industries and are considered as toxic to humans. Limited information is available on the dynamics of Ga and In in soil-upland crop systems. Therefore, this study aimed
Tiina Ujula et al.
Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging, 12(3), 259-268 (2009-10-03)
The aim of the study was to compare (68)Ga-chloride with 2-[(18)F]fluoro-2-deoxy-D: -glucose (FDG) for the imaging of pancreatic xenografts. Rats with subcutaneous human pancreatic adenocarcinoma xenografts were evaluated in vivo by dynamic positron emission tomography (PET) and ex vivo by
Amir R Jalilian et al.
Acta pharmaceutica (Zagreb, Croatia), 59(4), 421-429 (2009-11-19)
beta-Human chorionic gonadotropin (beta-hCG) was successively labeled with [(67)Ga]-gallium chloride after conjugation with freshly prepared diethylenetriaminepentaacetic acid dianhydride (ccDTPA). After solid phase purification of the radiolabeled hormone, high performance liquid chromatography showed radiochemical purity higher than 95 % under optimized
C Caraco et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 49(12), 1477-1479 (1998-09-24)
Previous studies report that deferoxamine (DFO) binds metallic ions such as Fe3+, In3+ and Ga3+ with very high affinity. This property of DFO has been utilized to label DFO-coupled compounds with radiometals such as 67Ga and 111In. We have studied
James M Hogg et al.
Dalton transactions (Cambridge, England : 2003), 46(35), 11561-11574 (2017-08-03)
Coordination complexes of Lewis acidic metal chlorides AlCl

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