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361755

Sigma-Aldrich

(1,5-Cyclooctadiene)bis(triphenylphosphine)rhodium(I) hexafluorophosphate dichloromethane complex (1:1)

Synonym(s):

NSC 179445

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About This Item

Empirical Formula (Hill Notation):
C45H44Cl2F6P3Rh
CAS Number:
35238-97-2
Molecular Weight:
965.55
MDL number:
MFCD02091684
UNSPSC Code:
12352300
PubChem Substance ID:
24862254
NACRES:
NA.22

reaction suitability

core: rhodium
reagent type: catalyst

mp

215 °C (lit.)

SMILES string

[Rh+].ClCCl.F[P-](F)(F)(F)(F)F.[CH]1[CH]CC[CH][CH]CC1.c2ccc(cc2)P(c3ccccc3)c4ccccc4.c5ccc(cc5)P(c6ccccc6)c7ccccc7

InChI

1S/2C18H15P.C8H12.CH2Cl2.F6P.Rh/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-4-6-8-7-5-3-1;2-1-3;1-7(2,3,4,5)6;/h2*1-15H;1-2,7-8H,3-6H2;1H2;;/q;;;;-1;+1/b;;2-1-,8-7-;;;

InChI key

FCVRPQBVWYQXFH-ISVFTUMHSA-N

Application

Catalyst for:
  • Polycyclotrimerization reactions
  • Hydrosilylation and hydrogenation reactions
  • Hydroformylation reactions
  • Regioselective di- and trisilylation reactions
  • Mannich and nitro-Mannich reactions
  • Reductive alkylation reactions

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Chemistry Letters (Jpn), 881-881 (1988)
L Pauling
Proceedings of the National Academy of Sciences of the United States of America, 86(5), 1431-1433 (1989-03-01)
Consideration of the relation between bond length and bond number and the average atomic volume for different ways of packing atoms leads to the conclusion that the average ligancy of atoms in a metal should increase when a phase change

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