250724
1,4,8,11-Tetrathiacyclotetradecane
95%
Synonym(s):
14-Ane-S4
Sign Into View Organizational & Contract Pricing
All Photos(1)
About This Item
Empirical Formula (Hill Notation):
C10H20S4
CAS Number:
Molecular Weight:
268.53
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
95%
mp
118-121 °C (lit.)
SMILES string
C1CSCCSCCCSCCSC1
InChI
1S/C10H20S4/c1-3-11-7-9-13-5-2-6-14-10-8-12-4-1/h1-10H2
InChI key
WMVHWZHZRYGGOO-UHFFFAOYSA-N
General description
1,4,8,11-Tetrathiacyclotetradecane is a tetradentate thioether and forms complexes with ruthenium. It is also referred as thio-crown [14]aneS(4) or sulfur crown-ether analog.
Application
1,4,8,11-Tetrathiacyclotetradecane has been used in liquid-liquid extraction of metal ions.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Customers Also Viewed
Liquid-liquid extraction of metal ions by the thiacrown compound 1, 4, 8, 11-tetrathiacyclotetradecane.
Saito K, et al.
Analytica Chimica Acta, 151, 447-455 (1983)
Sophie H Dale et al.
Acta crystallographica. Section C, Crystal structure communications, 61(Pt 6), o411-o413 (2005-06-03)
Investigations of the reactivity of the thio-crown [14]aneS(4) (1,4,8,11-tetrathiacyclotetradecane) towards the aminating agent o-mesitylsulfonylhydroxylamine have lead to the crystallization of 1lambda(4),4lambda(4),8lambda(4),11lambda(4)-tetrathiacyclotetradecane-1,4,7,10-tetraylidenetetraaminium tetrakis(2,4,6-trimethylbenzenesulfonate), C10H28N4S(4)4+.4C9H11O3S-. The compound crystallizes in a centrosymmetric space group, with half a formula unit in the asymmetric unit.
Siu-Chung Chan et al.
Inorganic chemistry, 50(22), 11636-11643 (2011-10-26)
Ruthenium complexes containing 2-(2-nitrosoaryl)pyridine (ON(^)N) and tetradentate thioether 1,4,8,11-tetrathiacyclotetradecane ([14]aneS4), [Ru(ON(^)N)([14]aneS4)](2+) [ON(^)N = 2-(2-nitrosophenyl)pyridine (2a), 10-nitrosobenzo[h]quinoline (2b), 2-(2-nitroso-4-methylphenyl)pyridine, (2c), 2-(2-nitrosophenyl)-5-(trifluoromethyl)pyridine (2d)] and analogues with the 1,4,7-trithiacyclononane ([9]aneS3)/tert-butylisocyanide ligand set, [Ru(ON(^)N)([9]aneS3)(C≡N(t)Bu)](2+) (4a and 4b), have been prepared by insertion of a
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service